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A highly selective chemosensor for the detection of Cu through the formation of coordination polymer
Authors:Xiang Zhang  Jie Fu  Tian-Guang Zhan  Xiao-Zhong Wang  Liyan Dai  Yingqi Chen  Xin Zhao
Institution:1. Department of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310027, China;2. Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Lu, Shanghai 200032, China
Abstract:A highly selective chemosensor (1) bearing three salphen pockets fulfilled the recognition of Cu2+ via obvious color change and significant absorption enhancement upon the introduction of Cu2+. Additionally, the coordination of 1 and Cu2+ led to the formation of coordination polymer which further generated nanospheres, as evidenced by SEM, TEM, AFM, PXRD, and EDX investigations.
Keywords:Salphen  Recognition  Copper  Self-assembly  Coordination polymer
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