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BP神经网络用于总氮测定过程中I-、Br-的干扰消除
引用本文:马仁坤,余震虹,鱼瑛,赵玲君.BP神经网络用于总氮测定过程中I-、Br-的干扰消除[J].光谱实验室,2011,28(2):517-521.
作者姓名:马仁坤  余震虹  鱼瑛  赵玲君
作者单位:江南大学通信与控制工程学院通信研究所,江苏省无锡市蠡湖大道1800号,214122
摘    要:在碱性过硫酸钾消解-紫外分光光度法测定水体总氮过程中,碘离子和溴离子的存在会对测定结果产生干扰。针对这一现象,提出采用BP神经网络建立NO3-、I-、Br-含量的预测模型,经过训练后的预测模型能够较准确的预测到NO3-、I-、Br-的含量,从而消除I-、Br-对总氮测定的干扰。此法不需要物理和化学的分离,分析速度快,精度较高,可以消除总氮测定过程中的I-、Br-干扰,有很好的应用价值。

关 键 词:BP人工神经网络  紫外光谱  总氮  I-  Br-

Elimination of Interference from Br~-,I~- in the Process of Determination of Total Nitrogen Base on BP Neural Network
MA Ren-Kun,YU Zhen-Hong,YU Ying,ZHAO Ling-Jun.Elimination of Interference from Br~-,I~- in the Process of Determination of Total Nitrogen Base on BP Neural Network[J].Chinese Journal of Spectroscopy Laboratory,2011,28(2):517-521.
Authors:MA Ren-Kun  YU Zhen-Hong  YU Ying  ZHAO Ling-Jun
Institution:MA Ren-Kun YU Zhen-Hong YU Ying ZHAO Ling-Jun(Institute of Communication,School of Communications and Control Engineering,Jiangnan University,Wuxi,Jiangsu 214122,P.R.China)
Abstract:In the process of determination of total nitrogen by UV spectrophotometry with potassium peroxydisulfate in alkaline solution,the iodine ion and bromine ion in solution will interfere the result.In response to this phenomenon,a prediction model using BP neural network was established to predict the content of NO-3,I-,Br-.The prediction model was trained,and can more accurately predicate content of NO-3,I-,Br-with the eliminations of interference from Br-,I-on the determination of total nitrogen.This method ...
Keywords:I-  Br-
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