Asymmetrische Hg(II)-Komplexe mit Organothiolato- bzw. Organoselenolato-und Triazenato-Liganden |
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Authors: | Paul Peringer |
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Institution: | (1) Institut für Anorganische und Analytische Chemie, Universität Innsbruck, A-6020 Innsbruck, Austria |
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Abstract: | The mixed mercury complexes (2XC6H4)2N3HgY (X=CH3, F, Cl, Br, I;Y=SC2H5, SC6H5, SeC6H5) have been prepared. Both the Hg–S and Hg–Se bonds and, in contrast to other mixed triazenato-mercury compounds, the triazenato-mercury bonds have been shown to be kinetically labile on the NMR time scale by means of77Se and199Hg NMR spectroscopy. Evidence has been obtained for the presence of (2XC6H4)2N3HgY together with HgY
2 and (2XC6H4)2N3]2Hg in solution. |
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Keywords: | Mercury Selenolato Thiolato Triazenato |
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