Anomalous reorganization free energies in optical electron transfer in solution |
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| Authors: | Paul Delahay |
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| Institution: | Department of Chemistry, New York University, New York, New York 10003, USA |
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| Abstract: | Autoionization bands are observed in the photoelectron emission spectroscopy of aqueous solutions of cyanometalate complexes (Mn, Fe, W, Mo), anions (NO3, CIO−4 and cations (Ag+ TI+. Reorganization free energies for autoionization bands are anomalously low in absolute value (by≈1 eV) in comparison with direct transitions to the continuum. Interpretation is based on potential energy profiles and model calculations for the reorganization free energy. |
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