Raman spectroscopy of (Fe,Li)-doped delafossite oxide CuCrO2 |
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Affiliation: | 1. Departamento de Física, Universidade Tecnológica Federal do Paraná, Campus Ponta Grossa, Avenida Monteiro Lobato 1787, 84.016-210, Ponta Grossa, Paraná, Brazil;2. Departamento de Física, Universidade Estadual de Ponta Grossa, Av. Gen. Carlos Cavalcanti 4748, 84.030-000, Ponta Grossa, Paraná, Brazil;1. Department of Chemical, Biological, Pharmaceutical and Environmental Sciences, University of Messina, Viale D’Alcontres 31, 98166, Messina, Italy;2. Laboratoire de Chimie Physique, UMR8000, Université Paris Sud, 91405, Orsay cedex, France;3. ISIS Facility, STFC Rutherford Appleton Laboratory, Chilton, Oxon, OX11 0QX, UK;4. Department of Chemistry and Biochemistry, Texas Tech University, Box 41061, Lubbock, TX 79409, USA;5. Theoretical Division, Los Alamos National Laboratory, Los Alamos, NM, 87545, USA;6. Department of Mathematical and Informatics Sciences, Physical Sciences and Earth Sciences, University of Messina, Viale D’Alcontres 31, 98166, Messina, Italy;1. Key Laboratory of High-temperature and High-pressure Study of the Earth’s Interior, Institute of Geochemistry, Chinese Academy of Sciences, Guiyang, Guizhou 550081, China;2. University of Chinese Academy of Sciences, Beijing 100049, China;3. Institute of Earth Sciences, Academia Sinica, Taipei 115, Taiwan;1. Laboratório de Nanoestruturas Plasmônicas – LabNano, Departamento de Química, ICE, Universidade Federal de Juiz de Fora, 36036-900 Juiz de Fora, MG, Brazil;2. Museu de Arte Murilo Mendes, Universidade Federal de Juiz de Fora, 36036-900 Juiz de Fora, MG, Brazil;1. Uzhhorod National University, 46 Pidhirna Str., 88000, Uzhhorod, Ukraine;2. Vlokh Institute of Physical Optics, 23 Dragomanov Str., 79005, Lviv, Ukraine;3. Semiconductor Physics, Chemnitz University of Technology, D-09107, Chemnitz, Germany;4. Institute of Electron Physics, Ukr. Nat. Acad. Sci., 21 Universytetska Str., 88017, Uzhhorod, Ukraine;1. Escuela Técnica Superior de Ingeniería del Diseño, Universitat Politècnica de València, València, Spain;2. Instituto de Energía Solar, ETSI Telecomunicación, Universidad Politécnica de Madrid, Ciudad Universitaria, Madrid, Spain;3. Laboratory MANAPSE, University Mohammed V in Rabat, Morocco |
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Abstract: | In this paper we investigated the vibrational properties of (Fe,Li)-doped delafossite oxide CuCrO2 by means of Raman experiments. The measurements were carried out at ambient temperature and pressure and on ab- and a(b)c-plane of a single grain. The samples were prepared using self-combustion urea nitrate process and the structure of all samples was checked using X-ray diffraction. All peaks were indexed as arising from CuCrO2 delafossite with space group R-3 m. Active phonon modes with A1g and Eg symmetries were identified as well as the presence of one additional line that could not be associated with inhomogeneities at microscopic level. The frequencies of the A1g and Eg modes were also observed to be independent upon Fe and Li doping, but not the corresponding scattering intensities. |
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Keywords: | Delafossite Raman spectroscopy Doped |
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