Application de la RMN du 13C a la determination de la configuration de centres quaternaires en serie alicyclique et hydrate de carbone a chaine ramifiee |
| |
Authors: | A.M. Sepulchre B. Septe G. Lukacs S.D. Gero W. Voelter E. Breitmaier |
| |
Affiliation: | Institut de Chimie des Substances Naturelles, C.N.R.S., 91190, Gif sur Yvette, France;Chemisches Institut der Universität, Wilhelmstrasse 33,74, Tübingen, Germany |
| |
Abstract: | Configurational assignments to quaternary centres of 2-(l,3-dithianyl) branched-chain carbohydrates, important intermediates for the synthesis of carbohydrate-containing antibiotics, have been made through natural abundance 13C NMR spectroscopy. Configurations of quaternary carbons in 21, 24 and 26 were assigned by comparison with 13C spectra of structurally-related alicyclic derivatives 1–16. |
| |
Keywords: | |
本文献已被 ScienceDirect 等数据库收录! |
|