Application de la RMN du 13C a la determination de la configuration de centres quaternaires en serie alicyclique et hydrate de carbone a chaine ramifiee |
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| Authors: | AM Sepulchre B Septe G Lukacs SD Gero W Voelter E Breitmaier |
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| Institution: | Institut de Chimie des Substances Naturelles, C.N.R.S., 91190, Gif sur Yvette, France;Chemisches Institut der Universität, Wilhelmstrasse 33,74, Tübingen, Germany |
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| Abstract: | Configurational assignments to quaternary centres of 2-(l,3-dithianyl) branched-chain carbohydrates, important intermediates for the synthesis of carbohydrate-containing antibiotics, have been made through natural abundance 13C NMR spectroscopy. Configurations of quaternary carbons in 21, 24 and 26 were assigned by comparison with 13C spectra of structurally-related alicyclic derivatives 1–16. |
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