Action du phenyltetrafluorophosphorane sur les α ou β hydroxy-esters, -cetones, -Nitriles, -ethers,et les nitroalcools. Acces a quelques derives fonctionnels α ou β fluores |
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| Authors: | DJ Costa NE Boutin JG Riess |
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| Institution: | Laboratoire de Chimie Minérale, Equipe de Recherche Associée au CNRS, Institut de Mathétiques et Sciences Physiques, Parc Valrose, 06034 Nice Cedex, France |
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| Abstract: | The reaction of phenyltetrafluorophosphorane with secondary or tertiary α- or β -hydroxy esters, ketones, nitriles, ethers and nitro derivatives has been investigated. The formation of the alkoxyfluorophosphorane 3 has been established in several cases. Good yields of isolated fluoro compounds were obtained with MeCHFCOOEt, MeCHFCH2COOEt and Me2CFCH2NO2. These compounds eliminate HF readily. |
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