Autoxidation of terpenic aldehydes—II |
| |
| Authors: | R. Caputo L. Previtera P. Monaco L. Mangoni |
| |
| Affiliation: | Institute of Organic Chemistry, University of Naples, via Mezzocannone 16, Italy |
| |
| Abstract: | The influence of steric factors on the autoxidation of aldehydes having tertiary formyl groups has been investigated. These afford nor-derivatives by loss of carbon monoxide, and carboxylic acids. Steric interactions have been shown to affect strongly the ratio between carboxylic acid and nor-derivatives and, in addition, to increase the autoxidation rate. For the first time, formation of formates from aldehydes by autoxidation conditions, has been demonstrated. |
| |
| Keywords: | |
| 本文献已被 ScienceDirect 等数据库收录！ |
|
