Proprietes des derives des tricyclo[6,n,0,02,7]trienes-2,4,6—IV : Reactivite des tricyclo[6,n,0,02,7]trienes-2,4,6 ols-1 en milieu acide |
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| Authors: | P. Caubere M.S. Mourad |
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| Affiliation: | Université de Nancy I. Laboratoire de Chimie Organique I, “Méthodes de Synthèse organique, milieux réactionnels”, Equipe de Recherche Associée au CNRS, Case Officielle 140,54037 Nancy Cedex, France |
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| Abstract: | The action of toluene-p-sulphonic acid on tri- and tetracyclic benzocyclobutenols leads to the corresponding olefins. In some cases, after rearrangement derivatives of anti-2,7- benzobicyclo[3,2,1]octene are obtained. A mechanism is proposed for this rearrangement. |
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