An unusual intramolecular Diels-Alder reaction |
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Authors: | EL Ghisalberti PR Jefferies TG Payne |
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Institution: | Department of Organic Chemistry, University of Western Australia, Nedlands, Western Australia, 6009 |
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Abstract: | The diene-ester (2) on heating undergoes an intramolecular Diels-Alder reaction via the intermediate (3). The β-alkyl furan moiety in 3 reacts as the dienophile adding to the cyclohexadiene unit to give 4. |
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