Electronic structure of sulphur compounds—VII photoelectron spectra of thiocarbonyl heterocycles |
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Authors: | C. Guimon G. Pfister-Guillouzo M. Arbelot M. Chanon |
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Affiliation: | Laboratoire de Chimie Structurale, I.U.R.S., 64016-PAU, France;Laboratoire de Chimie Organique A, Faculté des Sciences de St-Jerôme, 13013-Marseille, France;Ecole Normale Superiéure, Tunis, Tunisia |
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Abstract: | The photoelectron spectra of α-substituted thiocarbonyl heterocycles have been analysed. By observing the effects of methyl substitution on the spectra, it was possible to assign the first five bands. These assignments were confirmed by semi-empirical calculations (CNDO/S). |
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