Asymmetrical nonbridgehead nitrogen—IV : Chiroptical properties of the amines,N-chloroamines and cyanamides |
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| Authors: | RG Kostyanovsky IM Gella VI Markov ZE Samojlova |
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| Institution: | Institute of Chemical Physics, Academy of Sciences of the USSR, Moscow, USSR |
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| Abstract: | The ORD and CD spectra of 2-methyl-aziridine, azetidine, pyrrolidine, piperidine, their N-Me, N-Hal, N-CN derivatives as well as those of camphidine, N-methyl- and N-cyano-camphidine have been investigated. The possibility of application of the quadrant rule for N-chloroamines is discussed. A similar rule is proposed for the N-CN chromophore. |
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