Investigation of the tautomeric equilibrium of some phenylazonaphthols |
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Authors: | L. A. Gribov Yu. M. Dedkov A. V. Kotov |
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Affiliation: | (1) Vernadskii Institute of Geochemistry and Analytical Chemistry, Moscow |
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Abstract: | The tautomeric equilibrium of phenylazonaphthols was investigated by the HMO method and by IR spectroscopy. It was found that in the case of 4-phenylazo-1-naphthol the thermodynamic stability of the tautomers was approximately the same, in the case of 1-phenylazo-2-naphthol the naphthoquinone hydrazone tautomer was substantially more stable. |
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