Electron-deficient molybdenum/cobalt/sulfido clusters: Chemistry related to hydrodesulfurization (HDS) catalysis |
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| Authors: | M David Curtis |
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| Institution: | (1) Department of Chemistry, The University of Michigan, 48109-1055 Ann Arbor, Michigan |
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| Abstract: | The author's work on the reactions of Cp2Mo2Co2S3(CO)4 (1) and Cp2Mo2 Co2S4(CO)2 (2) with organosulfur compounds is reviewed. Reaction pathways that lead to C S bond scission are proposed, and the relexance of these results to HDS reactions mer commercial  CoMoS catalysts is discussed. |
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| Keywords: | Hydrodesulfurization HDS catalysis C S bond homolysis mechanism Mo/Co/S clusters |
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