Catalytic transformations of sulfur dioxide into organic sulfur compounds |
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Authors: | G Pelzer J Herwig W Keim R Goddard |
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Institution: | (1) Institute of Technical Chemistry and Oil Chemistry of Rhine-Westfal Technical Higher School in Aachen, Worringerweg 1, D-52074 Aachen, Germany;(2) Max Planck Institute of Coal Research, Kaiser-Wilhelm-Platz 1, D-45470 Mülheim/Ruhr, Germany |
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Abstract: | The applications of catalytic transformations of SO2 into sulfur-containing organic compounds, reported in the literature, are briefly reviewed. The authors' studies in this field of chemistry,viz., the hydrosulfination of alkenes, the synthesis of γ-oxo sulfonesvia hydrosulfination, and the synthesis of aromatic sulfinic acids from diazonium salts, are summarized. Current results on the synthesis of the new sulfinato complex Pd(SO2Ph)(Cl)dppp] and its hydrogenation to PhSO2H are presented, and a mechanism for the catalytic synthesis of sulfinic acids is proposed. The structure of (Pd(μ-Cl)(dppp)l2 2+(SO4)2?·4SO2 salt is studied by X-ray diffraction analysis. |
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Keywords: | sulfur dioxide catalysis hydrosulfination sulfinic acids γ -oxo sulfones sulfinate complexes structure of di[1 3-bis(diphenylphosphino)propane]di-μ -chlorodipalladium sulfate |
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