Helical structures architecture of l-{2-(4-hydroxy-phenyl)-1-[(pyren-1-ylmethyl)-carbamoxyl]-ethyl}-carbamic acid tert-butyl ester |
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| Authors: | Jinchong Xiao Shu Wang Huibiao Liu Wei Xu Daoben Zhu |
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| Institution: | Beijing National Laboratory for Molecular Sciences, Key Laboratory of Organic Solids, Center for Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080, PR China |
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| Abstract: | A new pyrenemethylamine substituted l-Boc-tyrosine derivative was synthesized and characterized. UV-vis, FL, CD, and light scattering experiments proved that the chiral molecules were able to self-assemble for formation of new aggregate structure. The SEM and AFM images indicated that the helical wires could be fabricated by π-π stacking interaction between adjacent pyrene molecules. |
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| Keywords: | Self-assembly Chiral Stacking Aggregation |
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