Double reductive cyclization: a facile synthesis of the indoloquinoline alkaloid cryptotackieine |
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Authors: | P.T. Parvatkar P.S. Parameswaran S.G. Tilve |
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Affiliation: | a National Institute of Oceanography, Dona Paula, Goa 403 207, India b Department of Chemistry, Goa University, Taleigao Plateau, Goa 403 206, India |
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Abstract: | A new synthesis of the indoloquinoline alkaloid cryptotackieine, isolated from Cryptolepis sanguinolenta, is described which involves a Perkin reaction, a tandem double reduction-double cyclization reaction followed by regioselective methylation at the quinoline nitrogen. |
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Keywords: | Indoloquinoline alkaloid Perkin reaction Cryptotackieine Neocryptolepine Tandem Reductive cyclization |
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