Alkyl radical hyperconjugation in phosphorus compounds |
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Authors: | A. V. Fokin M. A. Landau |
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Affiliation: | (1) Scientific-Research Institute for Biological Testing of Chemical Compounds, Kupavna |
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Abstract: | Conclusions The31P and19F chemical shifts in phosphorus compounds of various conformations vary with the number of hydrogen or fluorine atoms attached to the-C atom of the phosphorus atom alkyl or perfluoroalkyl radical. This effect can be explained in terms of alkyl radical hyperconjugation.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 2435–2439, September, 1976. |
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