New series of acridines and phenanthrolines: synthesis and characterization |
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Authors: | Amel Souibgui,Anne Gaucher,Jé rô me Marrot,Flavien Bourdreux,Faouzi Aloui,Bé chir Ben Hassine,Damien Prim |
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Affiliation: | 1. University of Versailles Saint-Quentin-en-Yvelines, Institut Lavoisier de Versailles UMR CNRS 8180, 45, avenue des Etats-Unis, 78035 Versailles cedex, France;2. Laboratoire de Synthèse Organique, Asymétrique et Catalyse Homogène, Faculté des sciences de Monastir, Avenue de l''Environnement, 5019 Monastir, Tunisia |
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Abstract: | New series of acridines and phenanthrolines have been prepared from β-chlorovinyl aldehydes and various aniline derivatives allowing the installation of valuable substituents, such as ketone, nitro or amino groups at the heterocyclic core. X-ray analyses confirmed the structures of acridines and phenanthrolines as well as the presence of partially hydrogenated rings and their crucial impact on the overall shape of the acridine-based architectures. 1H NMR revealed the helical behaviour of several acridine motives. Comparison of UV data between architectures and influence of number of partially hydrogenated rings is also described. |
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Keywords: | Acridine-based architectures Phenanthrolines |
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