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‘Interrupted’ diazotization of 3-aminoindoles and 3-aminopyrroles
Authors:Barbara Parrino  Virginia Spanò  Anna Carbone  Alessandra Montalbano  Paola Barraja  Peter Màtyus  Girolamo Cirrincione  Patrizia Diana
Institution:1. Dipartimento di Scienze e Tecnologie Biologiche Chimiche e Farmaceutiche, Via Archirafi 32, 90123 Palermo, Italy;2. Department of Organic Chemistry, Semmelweis University, Högyes E. u. 7, H-1092 Budapest, Hungary
Abstract:‘Interrupted’ diazotization of 3-aminoindoles and 3-aminopyrroles, achieved by quenching with cold water immediately after the addition of nitrite, led, in good yields, to stable compounds whose structures were identified to be the diazonium species with nitrate as the counter ion, which show no saline character.
Keywords:Amino pyrroles  Aminoindoles  Diazoindoles  Diazo pyrroles
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