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Ruthenium-catalysed oxidation of alcohols to amides using a hydrogen acceptor |
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| Authors: | Andrew J.A. Watson Russell J. Wakeham Aoife C. Maxwell Jonathan M.J. Williams |
| Affiliation: | 1. Department of Chemistry, University of Canterbury, 20 Kirkwood Avenue, Ilam, Christchurch 8041, New Zealand;2. Department of Chemistry, University of Bath, Claverton Down, Bath BA2 7AY, United Kingdom;3. GlaxoSmithKline Research and Development, Gunnels Wood Road, Stevenage SG1 2NY, United Kingdom |
| Abstract: | A wider investigation into the synthesis of secondary amides from primary alcohols using a hydrogen acceptor using commercially available [Ru(p-cymene)Cl2]2 with bis(diphenylphosphino)butane (dppb) as the catalyst. The report looks at over 50 examples with varying functionality and steric bulk, whilst also covering the first reported results using microwave heating to effect the transformation. |
| Keywords: | Ruthenium Oxidation Amide Alcohol |
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