Commutative reduction of aromatic ketones to arylmethylenes/alcohols by hypophosphites catalyzed by Pd/C under biphasic conditions |
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| Authors: | Carole Guyon,Marc Baron,Marc Lemaire,Florence Popowycz,Estelle Mé tay |
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| Affiliation: | 1. Equipe Catalyse Synthèse Environnement, Institut de Chimie et Biochimie Moléculaires et Supramoléculaires, UMR-CNRS 5246, Université de Lyon, Université Claude Bernard-Lyon 1, Bâtiment Curien, 43 boulevard du 11 Novembre 1918, F-69622 Villeurbanne Cedex, France;2. Equipe Chimie Organique et Bioorganique, Institut de Chimie et Biochimie Moléculaires et Supramoléculaires, UMR-CNRS 5246, Institut National des Sciences Appliquées (INSA Lyon), Bâtiment Jules Verne, 20 Avenue Albert Einstein, F-69621 Villeurbanne Cedex, France |
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| Abstract: | An efficient method is reported to reduce aromatic ketones selectively into arylmethylenes or alcohols with hypophosphites and Pd/C, depending on the selected conditions. This study could represent a promising alternative to the classical uses of standard hydrides or molecular hydrogen involved in reduction and deoxygenation procedures. |
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| Keywords: | Deoxygenation Reduction Palladium Hypophosphite Ketones |
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