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Fullerene containing norbornenes: synthesis and ring-opening metathesis polymerization |
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| Authors: | Mansur S Miftakhov Vladimir V Mikheev Seda A Torosyan Yuliya N Biglova Fanuza A Gimalova Vladimir M Menshov Akhat G Mustafin |
| Institution: | 1. Institute of Organic Chemistry, Ufa Scientific Centre of the Russian Academy of Sciences, Ufa 450054, Russian Federation;2. Bashkir State University, Ufa, Russian Federation;3. Zelinsky Institute of Organic Chemistry of the Russian Academy of Sciences, Moscow, Russian Federation |
| Abstract: | New norbornenes with the covalently bonded fullerene C60 have been prepared as monomers for ring-opening metathesis polymerization. Under the Grubbs catalyst these monomers smoothly enter homopolymerization as well as co-polymerization reactions with the parent ‘non-fullerene’ monomers. Homopolymers are insoluble in organic solvents whereas co-polymers obtained by 1:1 co-polymerization of the norbornenes with their ‘non-fullerene’ analogues are well soluble. |
| Keywords: | Fullerene Norbornenes Synthesis Polymers Co-polymers Metathesis polymerization |
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