Synthesis and tunable ion-recognition properties of novel macrocyclic triamides |
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Authors: | Ziyi Ge Xingye Zhang Shaojie Chen Ying Liu Ruixiang Peng Tsutomu Yokazawa |
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Institution: | 1. Ningbo Institute of Materials Technology and Engineering (NIMTE), Chinese Academy of Sciences (CAS), Ningbo 315201, PR China;2. Department of Material and Life Chemistry, Kanagawa University, Rokkakubashi, Kanagawa-ku, Yokohama 221-8686, Japan |
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Abstract: | In this work, we report synthesis of rigid macrocyclic triamides and their tunable ion-recognition properties as selective anion and metal receptors. Diphenylacetylene-containing cyclic triamide CTA-1b and three cyclic triamides bearing functional methoxy and pyrimidine moieties were prepared by Lithium Hexamethyldisilazide (LiHMDS)-assisted cyclocondesation. CTA-1b displayed strong binding affinity to Cl– and I– anions, while CTA-2b exhibited a good binding affinity to the La3+ and Eu3+ cations. The selective recognition ability of ions has been tuned by incorporating pyrimidine and methoxy groups into the macrocyclic amides. |
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Keywords: | Macrocyclic triamides Lithium hexamethyldisilazide (LiHMDS) Anion and metal receptors |
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