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Palladium-catalyzed carbonylative synthesis of N-(2-cyanoaryl)benzamides and sequential synthesis of quinazolinones |
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| Authors: | Xiao-Feng Wu Stefan Oschatz Muhammad Sharif Matthias Beller Peter Langer |
| Affiliation: | 1. Department of Chemistry, Zhejiang Sci-Tech University, Xiasha Campus, Hangzhou 310018, Zhejiang Province, People''s Republic of China;2. Leibniz-Institut für Katalyse e.V. an der Universität Rostock, Albert-Einstein-Str. 29a, 18059 Rostock, Germany;3. Universität Rostock, Institut für Chemie, Albert-Einstein-Str. 3a, 18059 Rostock, Germany;4. Department of Chemistry, Comsats Institute of Information Technology, 22060 Abbottabad, Pakistan |
| Abstract: | A convenient procedure for the synthesis of N-(2-cyanoaryl)benzamides has been developed. Using aryl bromides and 2-aminobenzonitriles as the substrates, Mo(CO)6 as the CO source, the desired amides were produced in good yields. Quinazolinones were produced in good yields in a sequential manner as well. |
| Keywords: | Palladium catalyst Carbonylation Mo(CO)6 Amide Quinazolinone |
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