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Synthesis and photovoltaic properties of novel C60 bisadducts based on benzo[2,1,3]-thiadiazole
Authors:Wangqiao Chen  Qian Zhang  Teddy Salim  Sandy Adhitia Ekahana  Xiangjian Wan  Tze Chien Sum  Yeng Ming Lam  Alfred Hon Huan Cheng  Yongsheng Chen  Qichun Zhang
Affiliation:1. School of Materials Science and Engineering, Nanyang Technological University, 50 Nanyang Avenue, Singapore 639798, Singapore;2. Institute for Sports Research, Nanyang Technological University, 50 Nanyang Avenue, Singapore 639798, Singapore;3. Institute of Functional Polymer Materials, Center for Nanoscale Science & Technology, Nankai University, Tianjin 300071, PR China;4. School of Physical and Mathematical Sciences, Nanyang Technological University, 21 Nanyang Link, Singapore 637371, Singapore
Abstract:A novel C60 solar cell acceptor (BTOQC, benzo[2,1,3]-thiadiazole-o-quinodimethane-C60 bisadducts) based on benzo[2,1,3]thiadiazole has been synthesized as model to study how the thiadiazole group will affect the device performance in bulk heterojunction organic photovoltaics (BHJ-OPV) with poly(3-hexylthiophene) (P3HT) as donor. The optoelectronic, electrochemistry, and photovoltaic properties of the novel bisadduct BTOQC have been fully investigated. The best device performance of this fullerene derivative in our research was obtained as 2.50% with a high Voc of 0.74 V.
Keywords:Photovoltaic   C60   Solar cell acceptor   Benzo[2,1,3]thiadiazole
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