Synthesis and photovoltaic properties of novel C60 bisadducts based on benzo[2,1,3]-thiadiazole |
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Authors: | Wangqiao Chen Qian Zhang Teddy Salim Sandy Adhitia Ekahana Xiangjian Wan Tze Chien Sum Yeng Ming Lam Alfred Hon Huan Cheng Yongsheng Chen Qichun Zhang |
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Affiliation: | 1. School of Materials Science and Engineering, Nanyang Technological University, 50 Nanyang Avenue, Singapore 639798, Singapore;2. Institute for Sports Research, Nanyang Technological University, 50 Nanyang Avenue, Singapore 639798, Singapore;3. Institute of Functional Polymer Materials, Center for Nanoscale Science & Technology, Nankai University, Tianjin 300071, PR China;4. School of Physical and Mathematical Sciences, Nanyang Technological University, 21 Nanyang Link, Singapore 637371, Singapore |
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Abstract: | A novel C60 solar cell acceptor (BTOQC, benzo[2,1,3]-thiadiazole-o-quinodimethane-C60 bisadducts) based on benzo[2,1,3]thiadiazole has been synthesized as model to study how the thiadiazole group will affect the device performance in bulk heterojunction organic photovoltaics (BHJ-OPV) with poly(3-hexylthiophene) (P3HT) as donor. The optoelectronic, electrochemistry, and photovoltaic properties of the novel bisadduct BTOQC have been fully investigated. The best device performance of this fullerene derivative in our research was obtained as 2.50% with a high Voc of 0.74 V. |
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Keywords: | Photovoltaic C60 Solar cell acceptor Benzo[2,1,3]thiadiazole |
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