Participation of compact planar 1,3,5-tri(buta-2,3-dien-1-yl)-1,3,5-triazinane-2,4,6-trione in Pd(0) catalysed seven component cascade reactions delivers novel tunable molecular architecture |
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Authors: | Zeynep Gültekin Elghareeb E Elboray Moustafa F Aly Hussien H Abbas-Temirek Helena J Shepherd Ronald Grigg |
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Institution: | 1. Çank?r? Karatekin University, Department of Chemistry, 18100 Çank?r?, Turkey;2. Department of Chemistry, Faculty of Science at Qena, South Valley University, Qena, Egypt;3. Department of Chemistry, Bath University, Bath BA2 7AY, UK;4. Molecular Innovation, Diversity and Automated Synthesis (MIDAS) Centre, School of Chemistry, University of Leeds, Woodhouse Lane, Leeds LS6 9JT, UK |
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Abstract: | We report the spatially controlled, protecting group free, catalytic assembly of a library of nineteen 7-component cascade products generated from a novel planar trisallenyl 1,3,5-triazinane-2,4,6-trione core in combination with aryl iodides and amines with excellent regio and good stereoaselectivity for Z,Z,Z-isomers. |
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Keywords: | Palladium Stereoselective Tunable Multidirectional Peptides |
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