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Visible light photoredox catalysis: aerobic oxidation of perimidines to perimidinones |
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| Authors: | Chun-Ku Wu Teau-Jiuan Liou Hao-Yi Wei Pei-Shan Tsai Ding-Yah Yang |
| Institution: | 1. Department of Chemistry, Tunghai University, No. 1727, Sec. 4, Taiwan Boulevard, Xitun District, Taichung 40704, Taiwan;2. Department of Applied English, Chaoyang University of Technology, No. 168, Jifeng E. Rd., Wufeng District, Taichung 41349, Taiwan |
| Abstract: | Aerobic oxidation of a series of 2,3-dihydro-1H-perimidines to the corresponding 4- and 6-perimidinones via visible light photoredox catalysis using Ru(bpy)32+ as a catalyst was reported. The scope and limitation of this oxidation were investigated and a possible photochemical mechanism was proposed. |
| Keywords: | Visible light photoredox catalysis Perimidine Perimidinone Oxidation |
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