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Molecular complexity from aromatics. Studies on synthesis of polycyclic system related to crotogoudin
Authors:Tarun Kumar Behera  Vishwakarma Singh
Affiliation:Department of Chemistry, Indian Institute of Technology Bombay, Mumbai 400 076 India
Abstract:Synthesis of tricyclic systems related to crotogoudin from a simple aromatic precursor has been described. Oxidative dearomatization, tandem retro-Diels–Alder/Diels–Alder reaction and ring-closing metathesis are the key features of our approach.
Keywords:Diels&ndash  Alder reaction   Cycloaddition   Spiroepoxycyclohexa-2,4-dienone   Ring-closing metathesis
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