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Design and characterization of Bodipy derivatives for bulk heterojunction solar cells
Authors:Safacan Kolemen  Yusuf Cakmak  Tugba Ozdemir  Sule Erten-Ela  Muhammed Buyuktemiz  Yavuz Dede  Engin U Akkaya
Institution:1. UNAM-Institute of Materials Science and Nanotechnology, Bilkent University, Ankara 06800, Turkey;2. Institute of Solar Energy, Ege University, Izmir 35100, Turkey;3. Department of Chemistry, Gazi University, Ankara 06500, Turkey;4. Department of Chemistry, Bilkent University, Ankara 06800, Turkey
Abstract:Two electron rich Bodipy dyes with strong absorptivities in the visible region were designed and synthesized as potential electron donors in bulk heterojunction photovoltaic constructs. Overall efficiency is above 1%, with impressive responsiveness at both UV and near-IR ends of the visible spectrum. Computational studies reveal an unexpected effect of meso-substituents on the electron transfer efficiency.
Keywords:Bulk heterojunction solar cells  Bodipy  Near-IR sensitizers  Panchromaticity  Conversion efficiency
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