Synthesis of novel 2,4,6,8,10-pentaaza[3.3.3]propellane derivatives |
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Authors: | Moonyong Shin Myeong Hak Kim Tae-hwan Ha Jongho Jeon Kyoo-Hyun Chung Jin Seuk Kim Young Gyu Kim |
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Affiliation: | 1. Department of Chemical and Biological Engineering, Seoul National University, Seoul 151-744, Republic of Korea;2. Department of Chemistry, Inha University, Incheon 402-751, Republic of Korea;3. Agency for Defense Development, Daejeon 305-156, Republic of Korea |
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Abstract: | Propellanes and azapropellanes are attractive compounds for their unique structure and valuable applications but there are few synthetic studies for highly N-substituted azapropellanes. Several novel derivatives of 2,4,6,8,10-pentaaza[3.3.3]propellane, such as 3, 4, and 5 were successfully synthesized from readily available diethyl tartrate. Most of the synthetic steps were efficient. Their propellane structures were established by spectroscopic data and confirmed with single crystal X-ray analyses. |
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Keywords: | Heteropolycyclic compound Propellane Pentaazapropellane |
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