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Sequential dehydrogenation–arylation of diisopropylamine–borane complex catalyzed by palladium nanoparticles |
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| Authors: | Hélène DS Guerrand Ludovic D Marciasini Thomas Gendrineau Oana Pascu Samuel Marre Sandra Pinet Michel Vaultier Cyril Aymonier Mathieu Pucheault |
| Institution: | 1. Institut des Sciences Moléculaires, UMR 5255, Université de Bordeaux, IPB, CNRS, 351 Cours de la libération, F-33405 Talence cedex, France;2. CNRS, Univ. Bordeaux, ICMCB, UPR 9048, F-33600 Pessac, France |
| Abstract: | Palladium nanoparticles have been prepared using different techniques, CO2-assisted microfluidics coflow or thermolysis using ionic liquids. Both techniques displayed interesting activities in dehydrogenation of diisopropylamine–borane complex, and allowed performing a dehydrogenation–arylation sequence with the creation of a carbon–boron bond. |
| Keywords: | Palladium Nanoparticle Borane Catalysis Borylation |
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