N-Alkyl- and N-aryl-dithieno[3,2-b:2′,3′-d]pyrrole-containing organic dyes for efficient dye-sensitized solar cells |
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Authors: | Akhil Gupta Melissa MA Kelson Vanessa Armel Ante Bilic Sheshanath V Bhosale |
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Institution: | 1. Department of Materials Engineering, Faculty of Engineering, Monash University, Wellington Road, Clayton, 3800 Victoria, Australia;2. School of Applied Sciences, RMIT University, GPO Box 2476V, Melbourne, 3001 Victoria, Australia;3. Department of Chemistry, Faculty of Science, Monash University, Wellington Road, Clayton, 3800 Victoria, Australia;4. CSIRO Mathematics Informatics and Statistics, Bayview Avenue, Clayton, 3169 Victoria, Australia |
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Abstract: | Two new organic sensitizers, 2-cyano-3-(6-(4-(diphenylamino)phenyl)-4-(2-ethylhexyl)-4H-dithieno3,2-b:2′,3′-d]pyrrol-2-yl)acrylic acid and 2-cyano-3-(6-(4-(diphenylamino)phenyl)-4-(4-(hexyloxy)phenyl)-4H-dithieno3,2-b:2′,3′-d]pyrrol-2-yl)acrylic acid, consisting of electron donating (triphenylamine) and electron accepting (cyanoacrylic acid) functionalities linked by two different rigidified π-spacers, N-alkyl- and N-aryl-dithieno3,2-b:2′,3′-d]pyrrole, were designed, synthesized and applied for dye-sensitized solar cells, respectively. The materials were successfully synthesized through Knoevenagel condensation reactions. Ultraviolet–visible absorption spectra revealed that the use of either of rigidified π-spacer resulted in similar charge transfer transition, however, enhanced spectral response was observed when compared with an oligothiophene analogue. In terms of their photovoltaic performance, new dyes outperformed the reference bithiophene sensitizer when tested with nitrile-based and ionic liquid-based electrolytes. |
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Keywords: | Donor&ndash π-acceptor Dithienopyrrole Dye-sensitized solar cells Knoevenagel condensation |
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