Asymmetric aldol reaction using a very simple primary amine catalyst: divergent stereoselectivity by using 2,6-difluorophenyl moiety |
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Authors: | Yuya Tanimura Kenji YasunagaKaori Ishimaru |
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Institution: | Department of Chemistry, National Defense Academy, Hashirimizu 1-10-20, Yokosuka 239-8686, Japan |
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Abstract: | Asymmetric aldol reactions of aliphatic ketones or aldehydes with aromatic aldehydes or isatins were catalyzed by a very simple and flexible N-(2,6-difluorophenyl)-l-valinamide. Interestingly, stereochemical course of the reaction of hydroxyacetones or α-branched aliphatic aldehydes as aldol donors was different from that of cycloalkanones. |
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Keywords: | Aldol reaction Asymmetric catalysis Isatin Organocatalysis Valine |
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