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X-ray powder diffraction study of polytetrafluoroethylene
Authors:Yu. A. Lebedev  Yu. M. Korolev  V. M. Polikarpov  L. N. Ignat’eva  E. M. Antipov
Affiliation:1.Topchiev Institute of Petrochemical Synthesis,Russian Academy of Sciences,Moscow,Russia;2.Tambov State Technical University,Tambov,Russia;3.Institute of Chemistry, Far East Division,Russian Academy of Sciences,Vladivostok,Russia
Abstract:Samples of polytetrafluoroethylene were studied by X-ray diffraction. A quantitative X-ray powder diffraction analysis of three components of the polymer was performed for the first time. All samples of polytetrafluoroethylene were found to be three-phase and consist of one crystalline and two amorphous phases. One of the amorphous phases is composed of low-molecular-weight products. The structure of the latter phase was established for the first time by X-ray diffraction methods and computer simulation.
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