Tricarbonylmanganese(I)-lysozyme complex: a structurally characterized organometallic protein |
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| Authors: | Razavet Mathieu Artero Vincent Cavazza Christine Oudart Yohan Lebrun Colette Fontecilla-Camps Juan Carlos Fontecave Marc |
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| Institution: | Laboratoire de Chimie et Biologie des Métaux, Université Joseph Fourier, Grenoble, France. |
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| Abstract: | The reaction of the new and structurally characterized covalent {Mn(CO)(3)(H(2)O)(2)}(+)-lysozyme adduct with NiS(4) and NiN(2)S(2) complexes generates binuclear Ni-Mn complexes; relevance to the reactivity of the protein-bound {Fe(CO)(CN)(2)} intermediate during maturation of NiFe] hydrogenases is discussed. |
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