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Application of a poly(dithiocarbamate) resin to the determination of trace copper,iron and zinc in natural waters
Authors:M Carmen Yebra-Biurrun  Adela Bermejo-Barrera  Pilar Bermejo-Barrera
Institution:(1) Department of Analytical Chemistry, Nutrition and Bromatology, Chemistry Faculty, University of Santiago de Compostela, E-15706 Santiago de Compostela, Spain
Abstract:A chelating poly(dithiocarbamate) resin with macroreticular support is shown to be effective for the preconcentration of copper, iron and zinc in natural waters. The retained ions can be eluted efficiently in 5 ml of 8M nitric acid from 1–20-cm columns of resin.This poly(dithiocarbamate) resin is used for the preconcentration and determination of copper, iron and zinc by flame atomic absorption spectrophoto-metry. Common ions present in natural waters do not interfere. The detection limits were 0.50, 0.21 and 0.04 mgrg 1–1 for Cu, Fe and Zn respectively.
Keywords:poly(dithiocarbamate) resin  copper  iron  zinc  natural waters
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