Electrocatalytic reduction of organic halides with cobalt bipyridine complexes |
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| Authors: | Budnikova Yu H Kafiyatullina A G Kargin Yu M Sinyashin O G |
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| Institution: | (1) Kazan Research Center, Russian Academy of Sciences, A. E. Arbuzov Institute of Organic and Physical Chemistry, 8 ul. Akad. Arbuzova, 420088 Kazan, Russian Federation |
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| Abstract: | The electrocatalytic reduction of organic halides by the Nibpy]+complexes coordinationally unsaturated with bpy (at potentials of the first wave) and by the coordinationally saturated Nibpy2]–complexes (at potentials of the second wave) was observed. The apparent rate constant of the process decreased with an increase in the difference of the reduction potentials of the substrate and catalyst in a large range of the driving force of the process. |
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| Keywords: | cobalt complexes 2 2"-bipyridine organic halides homogeneous electrochemical catalysis sibunite |
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