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Synthesis of 3-Phenyl-6-formyl-3, 4-dihydro-2H-1, 3-benzoxazine
引用本文:Qi Chao RAN Qiao TIAN Yi GU. Synthesis of 3-Phenyl-6-formyl-3, 4-dihydro-2H-1, 3-benzoxazine[J]. 中国化学快报, 2006, 17(10): 1305-1308
作者姓名:Qi Chao RAN Qiao TIAN Yi GU
作者单位:Qi Chao RAN,Qiao TIAN,Yi GU State Key Laboratory of Polymeric Materials Engineering,College of Polymer Science and Engineering,Sichuan University,Chengdu 610065
摘    要:Benzoxazine is a novel class of thermosetting resins, which possesses lots of outstanding properties such as no by-products and near-zero shrinkage during polymerization as well as good molecular design flexibility1-2. Furthermore, polybenzoxazines (PBZs)…

关 键 词:苯并恶嗪 乙醛基 合成 席夫碱
收稿时间:2006-05-09

Synthesis of 3-Phenyl-6-formyl-3,4-dihydro-2H-1,3-benzoxazine
Qi Chao RAN,Qiao TIAN,Yi GU. Synthesis of 3-Phenyl-6-formyl-3,4-dihydro-2H-1,3-benzoxazine[J]. Chinese Chemical Letters, 2006, 17(10): 1305-1308
Authors:Qi Chao RAN  Qiao TIAN  Yi GU
Abstract:A novel benzoxazine monomer containing aldehyde group, 3-phenyl-6-formyl-3, 4-dihydro-2H-1, 3-benzoxazine (Ald-B), was synthesized via the Mannich condensation of formaldehyde, p-hydroxybenzaldehyde and aniline. Its structure was characterized by Fourier transform infrared spectroscopy (FTIR), proton nuclear magnetic resonance (1HNMR). The side reaction in the synthesis is discussed.
Keywords:Benzoxazine   aldehyde group   synthesis   Schiff base.
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