Complexes of diorganotins with bidentate ligands |
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| Affiliation: | 1. Department of Chemistry, National Institute of Technology Agartala, Jirania, Tripura (west)-799046, India;2. Department of Forestry, North Eastern Regional Institute of Science and Technology, Nirjuli, Arunachal Pradesh - 791109, India;3. Institute of General and Ecological Chemistry, Lodz University of Technology, 90-924 Lodz, Zeromskiego 116, Poland;4. Department of Chemistry, Manipur University, Canchipur - 795003, Imphal, Manipur, India |
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| Abstract: | The bidentate chelating agents 3-(2-pyridyl)-5,6- diphenyl-1,2,4-triazine, 1,10-phenanthroline and 2,2′-bipyridyl form 1:1 complexes with organotin dichlorides and diisothiocyanates. The complexes are assigned octahedral structures with trans hydrocarbon groups except for the diphenyltin diisothiocyanato complexes which are assigned octahedral structures with cis hydrocarbon groups and trans isothiocyanato groups. The assignments are made on the basis of electric dipole moment measurements. |
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