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The complexing of Np(V) by some inorganic ligands
Affiliation:1. Nuclear Fuel Cycle Program, Lawrence Livermore National Laboratory, L-223, P.O. Box 808, Livermore, CA 94550, United States;2. Sandia National Laboratories, Nuclear Waste Disposal Research and Analysis, P.O. Box 5800, MS 0779, Albuquerque, NM 87185, United States;1. Karlsruhe Institute of Technology, Institute for Nuclear Waste Disposal, P.O. Box 3640, 76021, Karlsruhe, Germany;2. Amphos21 Consulting S.L., Passeig de Garcia i Fària, 49-51, 1°-1a, E08019, Barcelona, Spain;3. Svensk Kärnbränslehantering AB, Box 3091, SE-169 03, Solna, Sweden;1. Department of Civil & Environmental Engineering & Earth Sciences, University of Notre Dame, 301 Stinson-Remick Hall, Notre Dame, IN, 46556, USA;2. Los Alamos National Laboratory, 1400 University Dr., Carlsbad, NM, 88220, USA
Abstract:The complexing of Np(V) with Cl, F, NO3, NO2, SO4−2, SCN and IO3 has been studied by the solvent extraction method using Dinonylnaphthalene sulphonic acid (DNNS) as the extractant. An attempt is made to establish existence of the complexes by solvent extraction and spectrophotometric studies.
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