Synthetic control leading to chiral compounds |
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| Authors: | Teruaki Mukaiyama Nobuharu Iwasawa Rodney W. Stevens Toru Haga |
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| Affiliation: | Department of Chemistry, Faculty of Science, The University of Tokyo, Tokyo 113, Japan |
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| Abstract: | A highly diastereoselective cross aldol reaction is developed using divalent tin enolates formed from stannous trifluoromethanesulfonate and carbonyl compounds. The reaction is extended to a highly enantioselective cross aldol reaction employing chiral diamines derived from (S)-proline as ligands. |
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