| 二烷基锡聚合物的研究——Ⅲ.顺丁烯二酸二丁基锡酯与丙烯酸甲酯、丙烯酸丁酯的共聚合 |
| |
| 引用本文： | 吴元辉,杨梅英,陈鸿熙.二烷基锡聚合物的研究——Ⅲ.顺丁烯二酸二丁基锡酯与丙烯酸甲酯、丙烯酸丁酯的共聚合[J].高分子学报,1991,0(5):625-630. |
| |
| 作者姓名： | 吴元辉 杨梅英 陈鸿熙 |
| |
| 作者单位： | 福建师范大学 350007 |
| |
| 摘 要： |
|
| 关 键 词： | 有机锡聚合物 丙烯酸酯 共聚合 |
| 收稿时间： | 1990-11-13 |
STUDIES ON THE DIALKYLTIN POLYMERS III. COPOLYMERIZATION OF DIBUTYLTIN MALEATE WITH METHYL ACRYLATE AND BUTYL ACRYLATE |
| |
| WU Yuan-hui,YANG Mei-ying,CHEN Hong-xi.STUDIES ON THE DIALKYLTIN POLYMERS III. COPOLYMERIZATION OF DIBUTYLTIN MALEATE WITH METHYL ACRYLATE AND BUTYL ACRYLATE[J].Acta Polymerica Sinica,1991,0(5):625-630. |
| |
| Authors: | WU Yuan-hui YANG Mei-ying CHEN Hong-xi |
| |
| Institution: | Fujian Teachers University; Fuzhou; Post code: 350007 |
| |
| Abstract: | Benzoyl peroxide (BPO) was used for initiator in copolymerization of dibutyltin maleate (DBTM, M2) with methyl acrylate (MA, M1) in benzene and the reactivity ratios of copolymerization r1 and r2 were found to be 12.67 and 0.03, respectively. But in copolymerization of DBTM (M2) with butyl acrylate (BA, M1) r1 and r2 were 11.1 and 0> respectively. The cc-polymerization conditions, such as amount of initiator, ratios of monomers and addition method of initiator were examined. Copolymers were characterized by 1H-NMR,IR,elemental and TG analyses. MA-DBTM copolymer is a white and brittle solid, while BA-DBTM copolymer is a transparent elastomer at room temperature. |
| |
| Keywords: | |
| 本文献已被 维普 等数据库收录！ |
| 点击此处可从《高分子学报》浏览原始摘要信息 |
| 点击此处可从《高分子学报》下载免费的PDF全文 |
|
