| 阴极材料LaFe0.8-xCuxNi0.2O3的合成和烧结性能 |
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| 引用本文： | 李嵩,文钟晟,季世军,孙俊才,程成.阴极材料LaFe0.8-xCuxNi0.2O3的合成和烧结性能[J].无机化学学报,2006,22(1):149-152. |
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| 作者姓名： | 李嵩 文钟晟 季世军 孙俊才 程成 |
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| 作者单位： | 大连海事大学材料工艺研究所,大连,116026 |
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| 基金项目： | 瑞典-亚洲国际合作计划 |
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| 摘 要： | LaFe0.8-xCuxNi0.2O3 (x=0.0~0.2) (LFCN), a new cathode material of solid oxide fuel cell (SOFC), was synthesized by Co-precipitation method using sodium bicarbonate. The lattice structures of samples with different x contents were characterized by XRD. Porosity and density of the porous LaFe0.8-xCuxNi0.2O3 (x=0.0~0.1) as a function of sintering temperature were investigated. It was found that the orthorhombic structure could be formed after calcination at 900 ℃ for 4 h. The particle size of LFCN was about 350 nm. The density of the porous LFCN increased with sintering temperature, but the opposite was true for the porosity. On the other hand, at the same sintering temperature, the porosity of LaFe0.8-xCuxNi0.2O3 (x=0.0~0.1) decreased with increasing x contents. It is indicated that the dopant of Cu on LaFe0.8Ni0.2O3 can facilitate the sintering of the materials. After sintering at 1 100 ℃ for 4 h, the porous LaFe0.7Cu0.1Ni0.2O3 was still with appropriate structure, and its porosity was 29%.
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| 关 键 词： | 阴极材料 LaFe0.8-xCuxNi0.2O3 共沉淀法 烧结性能 |
| 文章编号： | 1001-4861(2005)01-0149-04 |
| 收稿时间： | 2005-07-18 |
| 修稿时间： | 2005-09-20 |
Synthesis and Sintering of Cathode Materials LaFe0.8-xCuxNi0.2O3 |
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| LI Song,WEN Zhong-Sheng,JI Shi-Jun,SUN Jun-Cai and CHENG Cheng.Synthesis and Sintering of Cathode Materials LaFe0.8-xCuxNi0.2O3[J].Chinese Journal of Inorganic Chemistry,2006,22(1):149-152. |
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| Authors: | LI Song WEN Zhong-Sheng JI Shi-Jun SUN Jun-Cai and CHENG Cheng |
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| Institution: | Institute of Materials and Technology, Dalian Maritime University, Dalian, Liaoning 116026,Institute of Materials and Technology, Dalian Maritime University, Dalian, Liaoning 116026,Institute of Materials and Technology, Dalian Maritime University, Dalian, Liaoning 116026,Institute of Materials and Technology, Dalian Maritime University, Dalian, Liaoning 116026 and Institute of Materials and Technology, Dalian Maritime University, Dalian, Liaoning 116026 |
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| Abstract: | |
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| Keywords: | cathode material LaFe0 8-xCuxNi0 2O3 Co-precipitation method sintering |
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