Transformations of epoxyketones of the carane series using bases |
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Authors: | A N Karaseva V V Karlin I S Ikhtonova Z G Isaeva |
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Institution: | (1) A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Branch, Academy of Sciences of the USSR, USSR |
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Abstract: | Conclusions
-3,4-Epoxycarane-2,5-dione when treated with alcoholates and alkali in alcohol forms 3,6,6-trimethyl-2-oxobicyclo3. 1. 0]-3-hexen-4-yl-formic acid and -3,4-epoxycaran-2-on-5-ol, whereas in dioxane the first product is formed exclusively.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 677–679, March, 1984. |
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