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Transformations of epoxyketones of the carane series using bases
Authors:A N Karaseva  V V Karlin  I S Ikhtonova  Z G Isaeva
Institution:(1) A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Branch, Academy of Sciences of the USSR, USSR
Abstract:Conclusions agr-3,4-Epoxycarane-2,5-dione when treated with alcoholates and alkali in alcohol forms 3,6,6-trimethyl-2-oxobicyclo3. 1. 0]-3-hexen-4-yl-formic acid andagr-3,4-epoxycaran-2-on-5-ol, whereas in dioxane the first product is formed exclusively.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 677–679, March, 1984.
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