Adsorption of methane and ethane, 1. Studies of work function changes of Pt foil. Effect of pressure |
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| Authors: | Zoltán Hlavathy and Pál Tétényi |
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| Affiliation: | (1) Boreskov Institute of Catalysis, 630090 Novosibirsk, Russia |
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| Abstract: | Liquid-phase hydrogenation of 3-thiolene-1,1-dioxide to thiolane-1,1-dioxide on Pd catalysts has been studied. According to the kinetic and adsorption data, at 20°C and PH 2=0.1–1.0 MPa the reaction proceedsvia the interaction of adsorbed 3-thiolene-1,1-dioxide with dissolved H2. At PH 2=2–7 MPa, the reaction between the adsorbed H2 and dissolved 3-thiolene-1,1-dioxide is the limiting step of the process. |
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| Keywords: | 3-thiolene-1,1-dioxide hydrogenation Pd catalysts |
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