首页 | 本学科首页   官方微博 | 高级检索  
     


Photophysics and photochemistry of new verdin compounds
Authors:Ralph S. Becker   Suresh Das   Sankar Chakravorti  Alan R. Morgan
Affiliation:

a Department of Chemistry, University of Houston, Houston, TX 77204-5641 U.S.A.

b Regional Research Laboratory, Trivandrum India

c Indian Association for the Cultivation of Science, Calcutta India

d Department of Chemistry and Medicinal Chemistry, University of Toledo, Toledo, OH 4360 U.S.A.

Abstract:Five different verdins, including one zinc metal chelate, were examined by laser flash techniques. Triplet molar absorption coefficients, triplet and singlet oxygen quantum yields and triplet lifetimes were determined. Zinc methyl pyroverdin (ZNMPV), copro II verdin trimethyl ester (CVTME) and deuteroverdin methyl ester (DVME) have the highest triplet and singlet oxygen quantum yields. ZNMPV and CVTME have the longest triplet lifetimes. Our data are consistent with singlet oxygen as the primary modality for phototherapy and it is suggested that DVME and CVTME may be useful agents.
Keywords:Verdins   phototherapy   triplet states   singlet oxygen   flash spectroscopy.
本文献已被 ScienceDirect 等数据库收录!
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号