Catalytic enantioselective Diels-Alder reaction via a chiral indium(III) complex |
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Authors: | Teo Yong-Chua Loh Teck-Peng |
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Institution: | Department of Chemistry, National University of Singapore, Singapore. |
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Abstract: | reaction: see text] A chiral indium complex has been developed to effect high enantioselectivities in catalyzing enantioselective Diels-Alder reaction. The cycloaddition of a variety of cyclic and open-chained dienes to 2-methacrolein and 2-bromoacrolein resulted in good yields and excellent enantioselectivities (up to 98% ee). |
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