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Synthesis of 1,3-Dialkylimidazolium and 1,3-Dialkylbenzimidazolium Salts
Authors:Starikova  O V  Dolgushin  G V  Larina  L I  Ushakov  P E  Komarova  T N  Lopyrev  V A
Institution:(1) Favorskii Irkutsk Institute of Chemistry, Siberian Division, Russian Academy of Sciences, ul. Favorskogo 1, Irkutsk, 664033, Russia
Abstract:A number of N-alkylimidazoles and N-alkylbenzimidazoles were synthesized by reactions of imidazole and benzimidazole with alkyl halides. The reaction rate increases by a factor of 2 to 3 under conditions of microwave activation. Subsequent treatment of the resulting N-alkylazoles with alkyl halides afforded the corresponding 1,3-dialkylimidazolium and 1,3-dialkylbenzimidazolium halides.
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